ABS is a program to determine the absolute configuration (hand) of the heavy atom substructure or polar space group using anomalous scattering. It also calculates a figure of merit which is a useful assessment of the heavy atom substructure. The algorithm is based on the Ps function method (Woolfson & Yao, 1994 and Hao & Woolfson, 1989).
The program can be used as soon as anomalous sites are determined, although the result may be more clear-cut after refinement of the sites.
TITLE, LABIN, RESOLUTION, ATOM
The value of C (the normalised value of C3, see reference below) is printed out. If this is positive, then the input atom configuration is likely correct. If it is negative, then it is likely incorrect.
The absolute value of C gives an indication of how well the substructure has been determined. C < 0.01 indicates a poor substructure solution, while C > 0.02 indicates a good substructure solution.
The program also outputs a figure of merit <|sin(phase_ha_substructure)|>
abs hklin /ccpdisk/xtal/ccp4/new_programs_4.2/hao_/ompdc.mtz <<eof TITLE determination of absolute configuration RESO 3.0 ATOM 0.88364 0.45255 0.20904 ATOM 0.78647 0.72103 0.20167 ATOM 0.84051 0.61635 0.11817 ATOM 0.72479 0.61860 0.11258 ATOM 0.72077 0.55255 0.14145 ATOM 0.59536 0.59265 0.24685 ATOM 0.86602 0.58829 0.40655 ATOM 0.77843 0.69468 0.11515 ATOM 0.75302 0.81095 0.19786 ATOM 0.69114 0.73137 0.22579 ATOM 0.61948 0.76388 0.20633 ATOM 0.54273 0.63876 0.12769 ATOM 0.63899 0.79544 -0.08076 ATOM 0.48613 0.55253 0.55323 ATOM 0.61479 0.44768 0.54001 ATOM 0.55872 0.43179 0.61568 ATOM 0.62674 0.45720 0.64670 ATOM 0.53478 0.56807 0.73165 ATOM 0.66755 0.78155 0.57921 LABIN F=F2 SIGF=SIGF2 DANO=DANO2 SIGDANO=SIGDANO2 eof
MacCHESS, Wilson Synchrotron Lab, Cornell University, NY 14850, USA
Email: qh22@cornell.edu